anharmonicity

基本解釋

After the calculation of frozen phonon method, we suppose that this difference is caused by the large anharmonicity of mode.
對(duì)于模，我們采用線性響應(yīng)計(jì)算的結(jié)果與實(shí)驗(yàn)值差別較大。
It works better than the [[quantum harmonic oscillator]] model, because it accounts for [[anharmonicity]], overtone frequencies, and combination frequencies.
相對(duì)[[量子諧振子]]模型，'''Morse 勢(shì)'''更真實(shí)，因?yàn)樗苊枋鯷[非諧效應(yīng)]]，倍頻，以及組合頻率。
The high-order terms added in the Hamiltonian expressionscan somewhat reduce the fitting deviations probably caused by the strong Renner-Teller effect, anharmonicity and Fermi resonance.
在該理論模型中增加的高階離心畸變項(xiàng)和高階微擾項(xiàng)可適當(dāng)?shù)亟档蚏enner-Teller效應(yīng)、非諧共振、Fermi共振等帶來的擬合的標(biāo)準(zhǔn)偏差。
Keywords Kink Anharmonicity Effective mass;
扭結(jié);非諧性;有效質(zhì)量;
local anharmonicity approximation
局域非簡(jiǎn)諧近似