nucleophilicity

基本解釋

In this paper, electroaffinity and nucleophilicity of organic compound have been investigated, and their application in organic synthesis also has been discussed.
從電性角度討論了有機物分子的親電性和親核性問題;并闡述了兩者在有機合成中的應用.
As steric hindrance of the aryl amine decreased and nucleophilicity increased, occurrence of the transfor-mation reaction increased and herbicidal activity of the product decreased.
芳胺空間位阻越小,親核性越強,副反應越容易發(fā)生,產(chǎn)物除草活性越低。
On the basis of equilibrated geometrical structure obtained by B3LYP/6-311G method,the nucleophilicity of-N(CH3)2 and-NH2 groups are investigated by electrostatic potential and MO calculations.
在B3LYP/6-311G計算所得的平衡幾何構(gòu)型基礎(chǔ)上,分別根據(jù)靜電勢和分子軌道計算研究了分子中-NH2和-N(CH3)2的親核性,并與偏二甲基肼和鹵代烴反應的實驗結(jié)果進行了對比分析。
The paper deals with the electrophilicity and nucleophilicity of organic chemicals and expounds the dialecti-al relation of the two. Their application in organic synthesis is also touehed upon.
從電性角度討論了有機物分子的親電性和親核性問題,闡述了兩者的辯證關(guān)系以及在有機合成中的應用。
Keywords Electroaffinity;Nucleophilicity;Electric property analysis;
電性分析;親電性;親核性;