steric hindrance effect

基本解釋

The dependence of chain scission and racemization on temperature results from molecular motion, "cage effect" and steric hindrance during recombination.
分子量降低和消旋作用對溫度的依賴性，是由于分子運動和籠罩效應以及重合的空間位阻效應所致。
Space steric hindrance resulted by length lateral chain and electrostatic repulsion of charged ion made the main contribution to water-reducing effect of PAA.
自制PAA 系列的減水機理主要為其長側鏈引起的空間位阻作用及其帶電離子的靜電斥力作用。
At the same time, we have also investigated the influence of the electric effect and steric hindrance effect of the substituents to the yields and regioselectivity.
同時，我們還研究了取代基團的電子效應和位阻效應對反應產(chǎn)率和區(qū)域選擇性的影響。